 |
2790 Canfields
Lane, Montoursville, PA 17754 CustomerService@Chemcoat.com
1.800.326.9471 |
| |
| material safety DATA SHEETS |
| Section 1 - Chemical Product and Company
Information |
| PRODUCT: ARMORCHEM 4500
RED PRIMER |
PRODUCT NUMBER:
41B-421A
|
ArmorChem
Manufactured by:
Chemcoat Inc.
P.O. Box 188
2790 Canfield Lane
Motoursville, PA 17754 |
IN CASE OF EMERGENCY:
Chem-tel
800-255-3924
Chemcoat, Inc.
800-326-9471 |
| Section 2 - Composition / Information on
Ingredients |
Other Exposure Limits
ACGIH Exposure Limits
OSHA Exposure Limits
Chemical Name / CAS No |
The OSHA TWA is 500
ppm (2,900 mg/m3).
ACGIH recommends a TWA
of 100 ppm (525 mg/m3).
NIOSH recommends a
TWA 350 mg/m3 and a
ceiling of 1,800 mg/m3)
not to be exceeded during
any 15 minute work
period.
Stoddard Solvent (1)
8052-41-3
24.68 percent
(1) NIOSH recommends a TWA 350 mg/m3 and a ceiling of
1,800 mg/m3) not to be exceeded during any 15
minute work period. The NIOSH IDLH level is 20,000 mg/m3.
Several states have set guidelines or standards
for Stoddard solvent in ambient air ranging from 5. |
| Section 3 - Hazards Identification |
-
-
0
2
2
HMIS Rating:
2
0
2
Routes of Entry:
Inhalation Skin Contact Eye Contact Ingestion
Exposure to this material may effect the following organs:
Blood Eyes Kidneys Liver Nervous System |
Effects of Overexposure, Stoddard Solvent:
Short Term Exposure
Inhalation: Causes irritation of the eyes and respiratory
tract. Exposure to levels
above 2,400 mg/m3 may cause headache, dizziness and nose
and throat irritation.
More severe exposures may cause nausea and vomiting, a
feeling of intoxication, weakness, muscle twitches and
in extreme cases convulsions, unconsciousness
and death.
Long Term Exposure
Prolonged or repeated contact with liquid may cause defatting
of the skin with
drying, irritation, and skin ulcers. Exposure to vapor
may cause eye, nose and
throat irritation, fatigue, headaches, anemia, jaundice,
and damage to the liver and
bone marrow. In animals: kidney damage. Repeated exposure
may cause a rare
reaction in some people that destroys blood cells (aplastic
anemia). This can be
fatal. Many petroleum-based solvents have been shown to
cause brain and/or
nerve damage. Effects may include reduced memory and concentration,
personality changes, fatigue, sleep disturbances, reduced
coordination, effects on
the autonomic nerves and/or nerves to the limbs.
Carcinogenicity: The following chemicals comprise 0.1%
or more of this mixture and are listed and/or classified
as
carcinogens or potential carcinogens by NTP, IARC, OSHA,
or ACGIH. |
| Section 4 - First Aid Measures |
INHALATION - Move person to fresh air. If
breathing has stopped, administer artifical respiration.
Seek medical
attention!
EYE CONTACT - In case of eye contact, flush the eyes with
water for fifteen (15) minutes. If contact lenses are
worn, quickly remove them, then flush the eyes with water.
Have a physician examine the eyes.
SKIN CONTACT - In case of skin contact, remove contaminated
clothing. Flush the skin with large amounts of water,
then wash the skin with soap and water.
INGESTION - Do not induce vomiting. This may cause chemical
pneumonitis and pulmonary edema. If vomiting occurs spontaneously,
keep the head below the hips to prevent aspiration of
liquid into the lungs. Seek immediate medical attention. |
| Section 5 - Fire Fighting Measures |
Section 5 - Fire Fighting Measures
Flash Point: 41 C (105 F)
LEL: 0.6 %
UEL: 8.0 % |
Extinguishing Media: Use carbon dioxide (CO2), foam,
dry chemical, or water spray/water fog extinguishing system.
Unusual Fire and Explosion Hazards: Vapors may travel
considerable distance by air and become ignited by ignition
sources.
Hazardous Combustion Products: Oxides of carbon
Fire Fighting Instructions: Full protective equipment
including self contained breathing apparartus should be
used.
Fire Equipment: Water spray may not be effective, use
fog nozzles |
| Section 6 - Accidental Release Measures |
Spill and Leak Precedure: Eliminate all
ignition sources. Ventilate the area. Use appropriate
respirator and protective clothing.
Small Spills: Contain spill areas with dikes. Recover
spilled material into containers. Absorb remainder with
absorbent material.
Large Spills: If small spill measures do not contain the
spill, notify local authorities and/or the fire department. |
| Section 7 - Handling and Storage |
Ventilation: Exhaust as required to keep
exposure below Threshold Limit Values
Protective Gear: If ventilation equipment cannot control
exposures below the TLV's, wear a properly fitted
organic/particulate NIOSH/MSHA approved respirator. Wear
rubber or neoprene protective gloves for repeated or prolonged
skin contact. Wear safety glasses or face shield for eye
protection. |
| Section 8 - Exposure Controls / Personal
Protection |
Ventilation: Exhaust as required to keep
exposure below Threshold Limit Values
Protective Gear: If ventilation equipment cannot control
exposures below the TLV's, wear a properly fitted
organic/particulate NIOSH/MSHA approved respirator. Wear
rubber or neoprene protective gloves for repeated or prolonged
skin contact. Wear safety glasses or face shield for eye
protection. |
| Section 9 - Physical and Chemical Properties |
Appearance: Liquid
Odor
Physical State: Liquid
Vapor Density: Heavier then air
Vapor Pressure: 1 mm Hg @ 14C
Evaporation Rate: Faster than ether
Boiling Range: 154 to 202 C
% Volume Volatile: 48.95
Specific Gravity (SG): 1.477
Lbs VOC/Gallon Solids: 6.18
Lbs/Gal VOC Less Exempt Less : water 3.15 |
| Section 10 - Stability and Reactivity |
Stability:
Stable
Incompatibility: heat or flames, strong acids or bases.
Strong oxidizing agents
Hazardous Decomposition: Oxides of carbon and nitrogen.
Oxides of carbon |
| Section 11 - Toxicological Information |
Stoddard Solvent
LC 50: No information found
LD 50: No information found |
| Section 12 - Ecological Information |
| Ecotoxicity: Protect environment from spills
and releases. |
| Section 13 - Disposal Considerations |
Disposal: As the US EPA, state, local or
other regulatory agency may have jurisdiction over the
disposal of your
facility's waste, it is incumbent on you, to learn and
satisfy all the regulations which effect you. Dispose
of in accordance to government regulations. |
| Section 14 - Transport Information |
HazardClass
UN Number
Proper Shipping Name
Packing Group
Agency
UN-1263
lll
Not Regul
DOT
Paint <119 gallon per single package
UN-1263
lll
3
DOT - Bulk
Paint >119 gallons in a single package |
| Section 15 - Regulatory Information |
Additional regulatory lisitings where applicable
SARA Section 313 Emission Reporting
95-63-6 1,2,4-Trimethylbenzene 0.56 percent
Toxic Substances Control Act (TSCA): All chemicals except
those listed below appear in the Toxic Substances Control
Act
Chemical Substance Inventory:- None |
| Section 16 - Other Information |
| Every effort has been made to ensure that
the safety information on this sheet is accurate, but
because Chemcoat, Inc. has no control over the condition
under which the product will be used, liability is limited
exclusively to replacement or refund of the purchased
price of this product. Except as stated herein, there
are NO EXPRESS OR IMPLIED WARRANTIES INCLUDING IMPLIED
WARRANTIES OF MERCHANTABILITY OR FINESS FOR A PARTICULAR
PURPOSE. Chemcoat, Inc. assumes no liability for injury
or incidental or consequential damages arising out of
the storage and handling or use of this product. |
| Close
Window |
| Section 1 - Chemical Product and Company
Information |
| PRODUCT: ARMORCHEM 3900
GRAY PRIMER |
PRODUCT NUMBER:
41G-471A
|
ArmorChem
Manufactured by:
Chemcoat Inc.
P.O. Box 188
2790 Canfield Lane
Montoursville, PA 17754 |
IN CASE OF EMERGENCY:
Chem-tel
800-255-3924
Chemcoat, Inc.
800-326-9471 |
| Section 2 - Composition / Information on
Ingredients |
Other Exposure Limits
ACGIH Exposure Limits
OSHA Exposure Limits
Chemical Name / CAS No |
The OSHA TWA is 500 ppm (2,900 mg/m3).
ACGIH recommends a TWA of 100 ppm (525 mg/m3).
NIOSH recommends a TWA 350 mg/m3 and a ceiling of 1,800
mg/m3) not to be exceeded during any 15 minute work period.
Stoddard Solvent (1)
8052-41-3
29.28 percent
The OSHA PELTWA, NIOSH TWA, DFG MAK, HSE TWA, and the
ACGIH TWA value is 100 ppm (435 mg/m3) for all isomers.
The OSHA PELTWA, NIOSH TWA, DFG MAK, HSE TWA, and the
ACGIH TWA value is 100 ppm (435 mg/m3) for all isomers.
The NIOSH, ACGIH, and HSE
STEL value is 150 ppm (655 mg/m3). The notation "skin"
is added to indicate the possibility of cutaneous absorption.
The NIOSH IDLH (all isomers) = 900 ppm.
Xylenes (o-,m-,p- isomers)
1330-20-7
2.58 percent
The OSHA legal limit and ACGIH value is 3.5 mg/m3 TWA.
The OSHA legal limit and
ACGIH value is 3.5 mg/m3 TWA.
NIOSH recommends that exposure to carbon black (as an
occupational carcinogen) be limited to the lowest feasible
concentrations. Also, NIOSH recommended airborne exposure
limit is 0.1 mg (PHA)/m3 . The NIOSH IDLH is 1,750 mg/m3.
In addition,
several states have set guidelines or standards for carbon
black in ambient air ranging from
117 µg/m3 (New York) to 35 µg/m3 (North Dakota)
Carbon Black
1333-86-4
0.179 percent
to 50 µg/m3 (Virginia) to 70 µg/m3 (Connecticut)
to 83 µg/m3 (Nevada).
(1) NIOSH recommends a TWA 350 mg/m3 and a ceiling of
1,800 mg/m3) not to be exceeded during any 15 minute work
period. The NIOSH IDLH level is 20,000 mg/m3. Several
states have set guidelines or standards for Stoddard solvent
in ambient air ranging from 5. |
| Section 3 - Hazards Identification |
-
-
0
2
2
HMIS Rating:
2
0
2
Routes of Entry:
Inhalation Skin Contact Eye Contact Ingestion
Exposure to this material may effect the following organs:
Blood Eyes Kidneys Liver Nervous System |
Effects of Overexposure, Xylenes (o-,m-,p- isomers):
Short Term Exposure
Inhalation: Exposure to vapor can be irritation to the
nose and throat. Inhalation
of vapor at concentrations above 200 ppm or 3 —
5 minutes can lead to xylene
intoxication. Symptoms include headache, dizziness, nausea
and vomiting. If
exposure should continue, central nervous system depression
characterized by
shallow breathing and weak pulse can occur. Levels of
230 ppm for 15 minutes
may cause lightheadedness without loss of equilibrium.
Reversible liver and
kidney damage in man has followed exposure to sudden high
concentrations of
vapor. Such high levels may also give rise to lung congestion.
Exposure to
extremely high concentrations (10,000 ppm or more) of
xylene vapors can lead to
a strong narcotic effect with symptoms of slurred speech,
stupor fatigue,
confusion, unconsciousness, coma, and possible death.
Long Term Exposure
Inhalation of xylene vapor and skin contact with liquid
are the two most probable
routes of long term exposure. Symptoms of inhalation are
dizziness, headache
and nausea. Long term exposure has been associated with
liver and kidney
damage, intestinal tract disturbances and central nervous
system depression.
Prolonged contact with skin can lead to irritation, dryness
and cracking. Repeated
exposure can cause poor memory, difficulty in concentration,
and other brain
effects. It can also cause damage to the eye surface.
Effects of Overexposure, Carbon Black:
Short Term Exposure
Inhalation may cause irritation to respiratory tract.
Skin contact may cause
irritation. Eye contact may cause irritation.
Long Term Exposure
Exposure to levels well above 3.5 mg/m3 for several months
may result in
damage to the skin and nails, temporary or permanent damage
to the lungs and
breathing passages, and adversely affect the heart. Carbon
Black containing PAH
greater than 0.1% should be considered a suspect carcinogen.
Lungs may be
affected by repeated or prolonged exposure at very high
concentrations: Some
Carbon blacks may contain compounds which are carcinogenic
and as organic
Effects of Overexposure, Carbon Black:
chemical compositions.
Effects of Overexposure, Stoddard Solvent:
Short Term Exposure
Inhalation: Causes irritation of the eyes and respiratory
tract. Exposure to levels
above 2,400 mg/m3 may cause headache, dizziness and nose
and throat irritation.
More severe exposures may cause nausea and vomiting, a
feeling of intoxication,
weakness, muscle twitches and in extreme cases convulsions,
unconsciousness
and death.
Long Term Exposure
Prolonged or repeated contact with liquid may cause defatting
of the skin with
drying, irritation, and skin ulcers. Exposure to vapor
may cause eye, nose and
throat irritation, fatigue, headaches, anemia, jaundice,
and damage to the liver and
bone marrow. In animals: kidney damage. Repeated exposure
may cause a rare
reaction in some people that destroys blood cells (aplastic
anemia). This can be
fatal. Many petroleum-based solvents have been shown to
cause brain and/or
nerve damage. Effects may include reduced memory and concentration,
personality changes, fatigue, sleep disturbances, reduced
coordination, effects on
the autonomic nerves and/or nerves to the limbs.
Carcinogenicity: The following chemicals comprise 0.1%
or more of this mixture and are listed and/or classified
as carcinogens or potential carcinogens by NTP, IARC,
OSHA, or ACGIH.
Carbon Black: (ACGIH) |
| Section 4 - First Aid Measures |
INHALATION - Move person to fresh air. If
breathing has stopped, administer artifical respiration.
Seek medical
attention!
EYE CONTACT - In case of eye contact, flush the eyes with
water for fifteen (15) minutes. If contact lenses are
worn, quickly remove them, then flush the eyes with water.
Have a physician examine the eyes.
SKIN CONTACT - In case of skin contact, remove contaminated
clothing. Flush the skin with large amounts of water,
then wash the skin with soap and water.
INGESTION - Do not induce vomiting. This may cause chemical
pneumonitis and pulmonary edema. If vomiting occurs spontaneously,
keep the head below the hips to prevent aspiration of
liquid into the lungs. Seek immediate medical attention. |
| Section 5 - Fire Fighting Measures |
Flash Point: 41 C (105 F)
LEL: 0.6 %
UEL: 8.0 % |
Extinguishing Media: Use carbon dioxide (CO2), foam,
dry chemical, or water spray/water fog extinguishing system.
Unusual Fire and Explosion Hazards: Vapors may travel
considerable distance by air and become ignited by ignition
sources.
Hazardous Combustion Products: Oxides of carbon
Fire Fighting Instructions: Full protective equipment
including self contained breathing apparartus should be
used.
Fire Equipment: Water spray may not be effective, use
fog nozzles |
| Section 6 - Accidental Release Measures |
Spill and Leak Precedure: Eliminate all
ignition sources. Ventilate the area. Use appropriate
respirator and protective clothing.
Small Spills: Contain spill areas with dikes. Recover
spilled material into containers. Absorb remainder with
absorbent material.
Large Spills: If small spill measures do not contain the
spill, notify local authorities and/or the fire department. |
| Section 7 - Handling and Storage |
Handling: Avoid prolonged breathing or contact
with product. Keep containers closed when not in use.
Do not cut, drill, grind, or weld near containers even
when empty. Use non-sparking tools when working around
this material.
Storage Requirements: Protect from freezing. Keep containers
closed when not in use. Keep away from excessive
heat, open flames, or sparks.
Regulatory Requirments: Consult national, state and local
environmental laws. |
| Section 8 - Exposure Controls / Personal
Protection |
Ventilation: Exhaust as required to keep
exposure below Threshold Limit Values
Protective Gear: If ventilation equipment cannot control
exposures below the TLV's, wear a properly fitted
organic/particulate NIOSH/MSHA approved respirator. Wear
rubber or neoprene protective gloves for repeated or prolonged
skin contact. Wear safety glasses or face shield for eye
protection. |
| Section 9 - Physical and Chemical Properties |
Appearance: Liquid
Odor
Physical State: Liquid
Vapor Density: Heavier then air
Vapor Pressure: 7 mm Hg @ 14C
Evaporation Rate: Faster than ether
Boiling Range: 137 to 202 C
% Volume Volatile: 57.22
Specific Gravity (SG): 1.334
Lbs VOC/Gallon Solids: 8.71
Lbs/Gal VOC Less Exempt Less: water 3.72 |
| Section 10 - Stability and Reactivity |
Stability: Stable
Incompatibility: heat or flames, strong acids or bases.
Strong oxidizing agents
Hazardous Decomposition: Oxides of carbon and nitrogen.
Oxides of carbon |
| Section 11 - Toxicological Information |
Stoddard Solvent
LC 50: No information found
LD 50: No information found
Xylenes (o-,m-,p- isomers)
LC 50: Inhalation- 26800 ppm
LD 50: Skin- 2000 mg/kg : Ingestion- 50 g/kg
Carbon Black
LD 50: oral: >8000 mg/kg |
| Section 12 - Ecological Information |
| Ecotoxicity: Protect environment from spills
and releases. |
| Section 13 - Disposal Considerations |
Disposal: As the US EPA, state, local or
other regulatory agency may have jurisdiction over the
disposal of your
facility's waste, it is incumbent on you, to learn and
satisfy all the regulations which effect you. Dispose
of in accordance to government regulations. |
| Section 14 - Transport Information |
HazardClass
UN Number
Proper Shipping Name
Packing Group
Agency
UN-1263
lll
Not Reg
DOT
Paint <119 gallons per single package
UN-1263
lll
3
DOT-Bulk
Paint >119 gallons per single package |
| Section 15 - Regulatory Information |
Additional regulatory lisitings where applicable
SARA Section 313 Emission Reporting
1330-20-7 Xylenes (o-,m-,p- isomers) 2.58 percent
95-63-6 1,2,4-Trimethylbenzene 0.68 percent
100-41-4 Ethylbenzene 0.60 percent
Toxic Substances Control Act (TSCA): All chemicals except
those listed below appear in the Toxic Substances Control
Act
Chemical Substance Inventory:- None |
| Section 16 - Other Information |
| Every effort has been made to ensure that
the safety information on this sheet is accurate, but
because Chemcoat, Inc. has no control over the condition
under which the product will be used, liability is limited
exclusively to replacement or refund of the purchased
price of this product. Except as stated herein, there
are NO EXPRESS OR IMPLIED WARRANTIES INCLUDING IMPLIED
WARRANTIES OF MERCHANTABILITY OR FINESS FOR A PARTICULAR
PURPOSE. Chemcoat, Inc. assumes no liability for injury
or incidental or consequential damages arising out of
the storage and handling or use of this product. |
| Close
Window |
| Section 1 - Chemical Product and Company
Information |
PRODUCT:
ArmorChem 1000SP Gray Primer
OBJECT FINISHED: Structural Steel |
PRODUCT NUMBER:
41X-358C
|
ArmorChem
Manufactured by:
Chemcoat Inc.
P.O. Box 188
2790 Canfield Lane
Motoursville, PA 17754 |
IN CASE OF EMERGENCY:
Chem-tel
800-255-3924
Chemcoat, Inc.
800-326-9471 |
| Section 2 - Composition / Information on
Ingredients |
Other Exposure Limits
ACGIH Exposure Limits
OSHA Exposure Limits
Chemical Name / CAS No
300 ppm; 1350 mg/m3
300 ppm |
Aliphatic Petroleum Distillates
64742-89-8
25.72 percent
The OSHA legal limit and ACGIH value is 3.5 mg/m3 TWA.
The OSHA legal limit and ACGIH value is 3.5 mg/m3 TWA.
NIOSH recommends that exposure to carbon black (as an
occupational carcinogen) be limited to the lowest feasible
concentrations. Also, NIOSH recommended airborne exposure
limit is 0.1 mg (PHA)/m3 . The NIOSH IDLH is 1,750 mg/m3.
In addition, several states have set guidelines or standards
for carbon black in ambient air ranging from 117 µg/m3
(New York) to 35 µg/m3 (North Dakota) to 50 µg/m3
(Virginia) to 70 µg/m3 (Connecticut) to 83 µg/m3
(Nevada).
Carbon Black
1333-86-4
0.198 percent |
| Section 3 - Hazards Identification |
-
-
0
3
2
HMIS Rating:
2
0
3
Routes of Entry:
Inhalation Skin Contact Eye Contact Ingestion
Exposure to this material may effect the following organs:
Blood Eyes Nervous System |
Effects of Overexposure, Carbon Black:
Short Term Exposure
Inhalation may cause irritation to respiratory tract.
Skin contact may cause
irritation. Eye contact may cause irritation.
Long Term Exposure
Exposure to levels well above 3.5 mg/m3 for several months
may result in
damage to the skin and nails, temporary or permanent damage
to the lungs and
breathing passages, and adversely affect the heart. Carbon
Black containing PAH
greater than 0.1% should be considered a suspect carcinogen.
Lungs may be
affected by repeated or prolonged exposure at very high
concentrations: Some
Carbon blacks may contain compounds which are carcinogenic
and as organic
extracts of these have been classified as possibly carcinogenic
to humans, special
care should be taken to avoid exposure to such extracts.
Lung effects remain
controversial and may be due to contaminants. It is probable
that minor effects
reported are non-specific effects associated with exposure
to nuisance dusts in
general. Polyaromatic hydrocarbons (PAH) are reportedly
present in some carbon
blacks. Depending on the process of manufacture, there
are variations in their
chemical compositions.
Carcinogenicity: The following chemicals comprise 0.1%
or more of this mixture and are listed and/or classified
as
carcinogens or potential carcinogens by NTP, IARC, OSHA,
or ACGIH.
Carbon Black: (ACGIH) |
| Section 4 - First Aid Measures |
INHALATION - Move person to fresh air. If
breathing has stopped, administer artifical respiration.
Seek medical
attention!
EYE CONTACT - In case of eye contact, flush the eyes with
water for fifteen (15) minutes. If contact lenses are
worn, quickly remove them, then flush the eyes with water.
Have a physician examine the eyes.
SKIN CONTACT - In case of skin contact, remove contaminated
clothing. Flush the skin with large amounts of water,
then wash the skin with soap and water.
INGESTION - Do not induce vomiting. This may cause chemical
pneumonitis and pulmonary edema. If vomiting occurs spontaneously,
keep the head below the hips to prevent aspiration of
liquid into the lungs. Seek immediate medical attention. |
| Section 5 - Fire Fighting Measures |
Flash Point: 14 C (57 F)
LEL: 0.9 %
UEL: 7.0 % |
Extinguishing Media: Use carbon dioxide (CO2), foam,
dry chemical, or water spray/water fog extinguishing system.
Unusual Fire and Explosion Hazards: Vapors may travel
considerable distance by air and become ignited by ignition
sources.
Hazardous Combustion Products: Oxides of carbon
Fire Fighting Instructions: Full protective equipment
including self contained breathing apparartus should be
used.
Fire Equipment: Water spray may not be effective, use
fog nozzles |
| Section 6 - Accidental Release Measures |
Spill and Leak Precedure: Eliminate all
ignition sources. Ventilate the area. Use appropriate
respirator and protective clothing.
Small Spills: Contain spill areas with dikes. Recover
spilled material into containers. Absorb remainder with
absorbent material.
Large Spills: If small spill measures do not contain the
spill, notify local authorities and/or the fire department. |
| Section 7 - Handling and Storage |
Handling: Avoid prolonged breathing or contact
with product. Keep containers closed when not in use.
Do not cut, drill, grind, or weld near containers even
when empty. Use non-sparking tools when working around
this material.
Storage Requirements: Protect from freezing. Keep containers
closed when not in use. Keep away from excessive
heat, open flames, or sparks.
Regulatory Requirments: Consult national, state and local
environmental laws. |
| Section 8 - Exposure Controls / Personal
Protection |
Ventilation: Exhaust as required to keep
exposure below Threshold Limit Values
Protective Gear: If ventilation equipment cannot control
exposures below the TLV's, wear a properly fitted
organic/particulate NIOSH/MSHA approved respirator. Wear
rubber or neoprene protective gloves for repeated or prolonged
skin contact. Wear safety glasses or face shield for eye
protection. |
| Section 9 - Physical and Chemical Properties |
Appearance: Liquid
Odor
Physical State: Liquid
Vapor Density: Heavier then air
Vapor Pressure: 2 mmHg @25C
Evaporation Rate: Faster than ether
Boiling Range: 118 to 150 C
% Volume Volatile: 50.02
Specific Gravity (SG): 1.353
Lbs VOC/Gallon Solids: 6.22
Lbs/Gal VOC Less Exempt Less : water 3.11 |
| Section 10 - Stability and Reactivity |
Stability: Stable
Incompatibility: heat or flames, strong acids or bases.
Strong oxidizing agents
Hazardous Decomposition: Oxides of carbon and nitrogen.
Oxides of carbon |
| Section 11 - Toxicological Information |
Aliphatic Petroleum Distillates
LC 50: >5000ppm/ 1 hour
LD 50: Oral >2000 mg/kg; Dermal >2000 mg/kg
Carbon Black
LD 50: oral: >8000 mg/kg |
| Section 12 - Ecological Information |
| Ecotoxicity: Protect environment from spills
and releases. |
| Section 13 - Disposal Considerations |
Disposal: As the US EPA, state, local or
other regulatory agency may have jurisdiction over the
disposal of your
facility's waste, it is incumbent on you, to learn and
satisfy all the regulations which effect you. Dispose
of in accordance to government regulations. |
| Section 14 - Transport Information |
HazardClass
UN Number
Proper Shipping Name
Packing Group
Agency
UN-1263
ll
Flamm Liq
DOT
Paint
*- Flammable liquid |
| Section 15 - Regulatory Information |
Additional regulatory lisitings where applicable
SARA Section 313 Emission Reporting
108-38-3 m-xylene 0.73 percent
100-41-4 Ethylbenzene 0.19 percent
1330-20-7 Xylenes (o-,m-,p- isomers) 259 PPM
71-43-2 Benzene 29 PPM
108-88-3 Toluene 23 PPM
Toxic Substances Control Act (TSCA): All chemicals except
those listed below appear in the Toxic Substances Control
Act
Chemical Substance Inventory:- None |
| Section 16 - Other Information |
| Every effort has been made to ensure that
the safety information on this sheet is accurate, but
because Chemcoat, Inc. has no control over the condition
under which the product will be used, liability is limited
exclusively to replacement or refund of the purchased
price of this product. Except as stated herein, there
are NO EXPRESS OR IMPLIED WARRANTIES INCLUDING IMPLIED
WARRANTIES OF MERCHANTABILITY OR FINESS FOR A PARTICULAR
PURPOSE. Chemcoat, Inc. assumes no liability for injury
or incidental or consequential damages arising out of
the storage and handling or use of this product. |
| Close
Window |
| Section 1 - Chemical Product and Company
Information |
PRODUCT:
ArmorChem 1000SP Red Oxide Primer |
PRODUCT NUMBER:
41X-359B
|
ArmorChem
Manufactured by:
Chemcoat Inc.
P.O. Box 188
2790 Canfield Lane
Motoursville, PA 17754 |
IN CASE OF EMERGENCY:
Chem-tel
800-255-3924
Chemcoat, Inc.
800-326-9471 |
| Section 2 - Composition / Information on
Ingredients |
Other Exposure Limits
ACGIH Exposure Limits
OSHA Exposure Limits
Chemical Name / CAS No
300 ppm; 1350 mg/m3
300 ppm |
Aliphatic Petroleum Distillates
64742-89-8
18.82 percent
The OSHA TWA is 500
ppm (2,900 mg/m3).
ACGIH recommends a TWA
of 100 ppm (525 mg/m3).
NIOSH recommends a
TWA 350 mg/m3 and a
ceiling of 1,800 mg/m3)
not to be exceeded during
any 15 minute work
period.
Stoddard Solvent (1)
8052-41-3
4.35 percent
(1) NIOSH recommends a TWA 350 mg/m3 and a ceiling of
1,800 mg/m3) not to be exceeded during any 15
minute work period. The NIOSH IDLH level is 20,000 mg/m3.
Several states have set guidelines or standards
for Stoddard solvent in ambient air ranging from 5. |
| Section 3 - Hazards Identification |
-
-
0
3
2
HMIS Rating:
2
0
3
Routes of Entry:
Inhalation Skin Contact Eye Contact Ingestion
Exposure to this material may effect the following organs:
Blood Eyes Kidneys Liver Nervous System |
Effects of Overexposure, Stoddard Solvent:
Short Term Exposure
Inhalation: Causes irritation of the eyes and respiratory
tract. Exposure to levels
above 2,400 mg/m3 may cause headache, dizziness and nose
and throat irritation.
More severe exposures may cause nausea and vomiting, a
feeling of intoxication,
weakness, muscle twitches and in extreme cases convulsions,
unconsciousness
and death.
Long Term Exposure
Prolonged or repeated contact with liquid may cause defatting
of the skin with
drying, irritation, and skin ulcers. Exposure to vapor
may cause eye, nose and
throat irritation, fatigue, headaches, anemia, jaundice,
and damage to the liver and
bone marrow. In animals: kidney damage. Repeated exposure
may cause a rare
reaction in some people that destroys blood cells (aplastic
anemia). This can be
fatal. Many petroleum-based solvents have been shown to
cause brain and/or
nerve damage. Effects may include reduced memory and concentration,
personality changes, fatigue, sleep disturbances, reduced
coordination, effects on
the autonomic nerves and/or nerves to the limbs.
Carcinogenicity: The following chemicals comprise 0.1%
or more of this mixture and are listed and/or classified
as
carcinogens or potential carcinogens by NTP, IARC, OSHA,
or ACGIH. |
| Section 4 - First Aid Measures |
INHALATION - Move person to fresh air. If
breathing has stopped, administer artifical respiration.
Seek medical
attention!
EYE CONTACT - In case of eye contact, flush the eyes with
water for fifteen (15) minutes. If contact lenses are
worn, quickly remove them, then flush the eyes with water.
Have a physician examine the eyes.
SKIN CONTACT - In case of skin contact, remove contaminated
clothing. Flush the skin with large amounts of water,
then wash the skin with soap and water.
INGESTION - Do not induce vomiting. This may cause chemical
pneumonitis and pulmonary edema. If vomiting occurs spontaneously,
keep the head below the hips to prevent aspiration of
liquid into the lungs. Seek immediate medical attention. |
| Section 5 - Fire Fighting Measures |
Flash Point: 14 C (57 F)
LEL: 0.6 %
UEL: 8.0 % |
Extinguishing Media: Use carbon dioxide (CO2), foam,
dry chemical, or water spray/water fog extinguishing system.
Unusual Fire and Explosion Hazards: Vapors may travel
considerable distance by air and become ignited by ignition
sources.
Hazardous Combustion Products: Oxides of carbon
Fire Fighting Instructions: Full protective equipment
including self contained breathing apparartus should be
used.
Fire Equipment: Water spray may not be effective, use
fog nozzles |
| Section 6 - Accidental Release Measures |
Spill and Leak Precedure: Eliminate all
ignition sources. Ventilate the area. Use appropriate
respirator and protective clothing.
Small Spills: Contain spill areas with dikes. Recover
spilled material into containers. Absorb remainder with
absorbent material.
Large Spills: If small spill measures do not contain the
spill, notify local authorities and/or the fire department. |
| Section 7 - Handling and Storage |
Handling: Avoid prolonged breathing or contact
with product. Keep containers closed when not in use.
Do not cut, drill, grind, or weld near containers even
when empty. Use non-sparking tools when working around
this material.
Storage Requirements: Protect from freezing. Keep containers
closed when not in use. Keep away from excessive
heat, open flames, or sparks.
Regulatory Requirments: Consult national, state and local
environmental laws. |
| Section 8 - Exposure Controls / Personal
Protection |
Ventilation: Exhaust as required to keep
exposure below Threshold Limit Values
Protective Gear: If ventilation equipment cannot control
exposures below the TLV's, wear a properly fitted
organic/particulate NIOSH/MSHA approved respirator. Wear
rubber or neoprene protective gloves for repeated or prolonged
skin contact. Wear safety glasses or face shield for eye
protection. |
| Section 9 - Physical and Chemical Properties |
Appearance: Liquid
Odor
Physical State: Liquid
Vapor Density: Heavier then air
Vapor Pressure: 3 mm Hg @ 14C
Evaporation Rate: Faster than ether
Boiling Range: 118 to 202 C
% Volume Volatile: 48.09
Specific Gravity (SG): 1.451
Lbs VOC/Gallon Solids: 5.86
Lbs/Gal VOC Less Exempt Less: water 3.03 |
| Section 10 - Stability and Reactivity |
Stability: Stable
Incompatibility: heat or flames, strong acids or bases.
Strong oxidizing agents
Hazardous Decomposition: Oxides of carbon and nitrogen.
Oxides of carbon |
| Section 11 - Toxicological Information |
Aliphatic Petroleum Distillates
LC 50: >5000ppm/ 1 hour
LD 50: Oral >2000 mg/kg; Dermal >2000 mg/kg
Stoddard Solvent
LC 50: No information found
LD 50: No information found |
| Section 12 - Ecological Information |
| Ecotoxicity: Protect environment from spills
and releases. |
| Section 13 - Disposal Considerations |
Disposal: As the US EPA, state, local or
other regulatory agency may have jurisdiction over the
disposal of your
facility's waste, it is incumbent on you, to learn and
satisfy all the regulations which effect you. Dispose
of in accordance to government regulations. |
| Section 14 - Transport Information |
HazardClass
UN Number
Proper Shipping Name
Packing Group
Agency
UN-1263
lll
Flamm Liq
DOT
Paint
*- Flammable liquid |
| Section 15 - Regulatory Information |
Additional regulatory lisitings where applicable
SARA Section 313 Emission Reporting
108-38-3 m-xylene 0.62 percent
100-41-4 Ethylbenzene 0.16 percent
67-56-1 Methyl Alcohol 0.13 percent
95-63-6 1,2,4-Trimethylbenzene 0.12 percent
1330-20-7 Xylenes (o-,m-,p- isomers) 179 PPM
71-43-2 Benzene 20 PPM
108-88-3 Toluene 16 PPM
Toxic Substances Control Act (TSCA): All chemicals except
those listed below appear in the Toxic Substances Control
Act
Chemical Substance Inventory:- None |
| Section 16 - Other Information |
| Every effort has been made to ensure that
the safety information on this sheet is accurate, but
because Chemcoat, Inc. has no control over the condition
under which the product will be used, liability is limited
exclusively to replacement or refund of the purchased
price of this product. Except as stated herein, there
are NO EXPRESS OR IMPLIED WARRANTIES INCLUDING IMPLIED
WARRANTIES OF MERCHANTABILITY OR FINESS FOR A PARTICULAR
PURPOSE. Chemcoat, Inc. assumes no liability for injury
or incidental or consequential damages arising out of
the storage and handling or use of this product. |
| Close
Window |
| Section 1 - Chemical Product and Company
Information |
PRODUCT:
ArmorChem 1500 Universal Gray |
PRODUCT NUMBER:
41X-361 |
Manufactured by:
Chemcoat Inc.
P.O. Box 188
2790 Canfield Lane
Motoursville, PA 17754 |
IN CASE OF EMERGENCY:
Chem-tel
800-255-3924
Chemcoat, Inc.
800-326-9471 |
| Section 2 - Composition / Information on
Ingredients |
Other Exposure Limits
ACGIH Exposure Limits
OSHA Exposure Limits
Chemical Name / CAS No |
The OSHA PELTWA, NIOSH TWA, DFG MAK, HSE TWA, and the
ACGIH
TWA value is 100 ppm (435 mg/m3) for all isomers.
The OSHA PELTWA, NIOSH TWA, DFG MAK, HSE TWA, and the
ACGIH TWA value is 100 ppm (435 mg/m3) for all isomers.
The NIOSH, ACGIH, and HSE STEL value is 150 ppm (655 mg/m3).
The notation "skin" is added to indicate the
possibility of cutaneous absorption. The NIOSH IDLH (all
isomers) = 900 ppm.
Xylenes (o-,m-,p- isomers)
1330-20-7
16.62 percent
The OSHA PEL is 100 ppm (435 mg/m3); there is no STEL.
The DFG MAK and the HSE TWA and the ACGIH TWA value is
100 ppm (435 mg/m3) and the STEL is 125 ppm (545 mg/m3).
The NIOSH IDLH level is 800 ppm. Several states have set
guidelines or standards for ethylbenzene in ambient air
ranging from 0.12 mg/m3 (Massachusetts) to 1.45 mg/m3
(New York) to 4.35 mg/m3 (Florida, South Carolina) to
4.35 – 5.45 mg/m3 (North Dakota) to 7.25 mg/m3 (Virginia)
to 8.7 mg/m3 (Connecticut) to 10.357 mg/m3 (Nevada). Ethylbenzene
100-41-4
4.99 percent
The OSHA TWA is 500 ppm (2,900 mg/m3). ACGIH recommends
a TWA of 100 ppm (525 mg/m3). NIOSH recommends a TWA 350
mg/m3 and a ceiling of 1,800 mg/m3) not to be exceeded
during any 15 minute work period.
Stoddard Solvent (1)
8052-41-3
2.13 percent
The OSHA legal limit and NIOSH recommends that Carbon
Black TWA.
(as an occupational carcinogen) be limited to the lowest
feasible concentrations. Also, NIOSH recommended airborne
exposure limit is 0.1 mg (PHA)/m3 . The NIOSH IDLH is
1,750 mg/m3. In addition, several states have set guidelines
or standards for carbon black in ambient air ranging from
117 µg/m3 (New York) to 35 µg/m3 (NorthDakota)
to 50 µg/m3 (Virginia) to 70 µg/m3 (Connecticut)
to 83 µg/m3 (Nevada). 0.201 percent(1) NIOSH recommends
a TWA 350 mg/m3 and a ceiling of 1,800 mg/m3) not to be
exceeded during any 15 minute work period. The NIOSH IDLH
level is 20,000 mg/m3. Several states have set guidelines
or standards
for Stoddard solvent in ambient air ranging from 5. |
| Section 3 - Hazards Identification |
-
-
0
3
2
HMIS Rating:
2
0
3
Routes of Entry:
Inhalation Skin Contact Eye Contact Ingestion
Exposure to this material may effect the following organs:
Blood Eyes Kidneys Liver Lungs Nervous System Skin |
Effects of Overexposure, Ethylbenzene:
Short Term Exposure
Ethyl benzene irritates the eyes, skin, and respiratory
tract. Exposure to high
concentrations can cause dizziness, lightheadedness and
unconsciousness. Very
high exposures (above the OEL) can cause difficult breathing,
narcosis, coma,
and even death. Swallowing the liquid may cause aspiration
into the lungs,
resulting in chemical pneumonitis. May affect the central
nervous system.
Concentration of 200 ppm can cause irritation.
Long Term Exposure
Repeated or prolonged exposure to the skin may cause drying,
scaling and
blistering. May cause kidney disease, liver disease, chronic
respiratory disease,
skin disease, as follows: EB is not nephrotoxic. Concern
is expressed because the
kidney is the primary route of excretion of EB and its
metabolites. EB is not
hepatotoxic. Since EB is metabolized by the liver, concern
is expressed for these
tissues. Exacerbation of pulmonary pathology might occur
following exposure to
EB. Individuals with impaired pulmonary function might
be at risk. EB is a
defating agent and may cause dermatitis following prolonged
exposure.
Individuals with preexisting skin problems may be more
sensitive to EB. There is limited evidence that EB may
damage the developing fetus, and may cause
mutations.
Effects of Overexposure, Xylenes (o-,m-,p- isomers):
Short Term Exposure
Inhalation: Exposure to vapor can be irritation to the
nose and throat. Inhalation
of vapor at concentrations above 200 ppm or 3 —
5 minutes can lead to xylene
intoxication. Symptoms include headache, dizziness, nausea
and vomiting. If
exposure should continue, central nervous system depression
characterized by
shallow breathing and weak pulse can occur. Levels of
230 ppm for 15 minutes
may cause lightheadedness without loss of equilibrium.
Reversible liver and
kidney damage in man has followed exposure to sudden high
concentrations of
vapor. Such high levels may also give rise to lung congestion.
Exposure to
extremely high concentrations (10,000 ppm or more) of
xylene vapors can lead to
a strong narcotic effect with symptoms of slurred speech,
stupor fatigue,
confusion, unconsciousness, coma, and possible death.
Long Term Exposure
Inhalation of xylene vapor and skin contact with liquid
are the two most probable
routes of long term exposure. Symptoms of inhalation are
dizziness, headache
and nausea. Long term exposure has been associated with
liver and kidney
damage, intestinal tract disturbances and central nervous
system depression.
Prolonged contact with skin can lead to irritation, dryness
and cracking. Repeated
exposure can cause poor memory, difficulty in concentration,
and other brain
effects. It can also cause damage to the eye surface.
Effects of Overexposure, Carbon Black:
Short Term Exposure
Inhalation may cause irritation to respiratory tract.
Skin contact may cause
irritation. Eye contact may cause irritation.
Long Term Exposure
Exposure to levels well above 3.5 mg/m3 for several months
may result in
damage to the skin and nails, temporary or permanent damage
to the lungs and
breathing passages, and adversely affect the heart. Carbon
Black containing PAH
greater than 0.1% should be considered a suspect carcinogen.
Lungs may be
affected by repeated or prolonged exposure at very high
concentrations: Some
Carbon blacks may contain compounds which are carcinogenic
and as organic
extracts of these have been classified as possibly carcinogenic
to humans, special
care should be taken to avoid exposure to such extracts.
Lung effects remain
controversial and may be due to contaminants. It is probable
that minor effects
reported are non-specific effects associated with exposure
to nuisance dusts in
general. Polyaromatic hydrocarbons (PAH) are reportedly
present in some carbon
blacks. Depending on the process of manufacture, there
are variations in their
chemical compositions.
Effects of Overexposure, Stoddard Solvent:
Short Term Exposure
Inhalation: Causes irritation of the eyes and respiratory
tract. Exposure to levels
above 2,400 mg/m3 may cause headache, dizziness and nose
and throat irritation.
More severe exposures may cause nausea and vomiting, a
feeling of intoxication,
weakness, muscle twitches and in extreme cases convulsions,
unconsciousness
and death.
Effects of Overexposure, Stoddard Solvent:
Long Term Exposure
Prolonged or repeated contact with liquid may cause defatting
of the skin with
drying, irritation, and skin ulcers. Exposure to vapor
may cause eye, nose and
throat irritation, fatigue, headaches, anemia, jaundice,
and damage to the liver and
bone marrow. In animals: kidney damage. Repeated exposure
may cause a rare
reaction in some people that destroys blood cells (aplastic
anemia). This can be
fatal. Many petroleum-based solvents have been shown to
cause brain and/or
nerve damage. Effects may include reduced memory and concentration,
personality changes, fatigue, sleep disturbances, reduced
coordination, effects on
the autonomic nerves and/or nerves to the limbs.
Carcinogenicity: The following chemicals comprise 0.1%
or more of this mixture and are listed and/or classified
as carcinogens or potential carcinogens by NTP, IARC,
OSHA, or ACGIH.
Carbon Black: (ACGIH) |
| Section 4 - First Aid Measures |
INHALATION - Move person to fresh air. If
breathing has stopped, administer artifical respiration.
Seek medical
attention!
EYE CONTACT - In case of eye contact, flush the eyes with
water for fifteen (15) minutes. If contact lenses are
worn, quickly remove them, then flush the eyes with water.
Have a physician examine the eyes.
SKIN CONTACT - In case of skin contact, remove contaminated
clothing. Flush the skin with large amounts of water,
then wash the skin with soap and water.
INGESTION - Do not induce vomiting. This may cause chemical
pneumonitis and pulmonary edema. If vomiting occurs spontaneously,
keep the head below the hips to prevent aspiration of
liquid into the lungs. Seek immediate medical attention. |
| Section 5 - Fire Fighting Measures |
Flash Point: 27 C (80 F)
LEL: 0.6 %
UEL: 8.0 % |
Extinguishing Media: Use carbon dioxide (CO2), foam,
dry chemical, or water spray/water fog extinguishing system.
Unusual Fire and Explosion Hazards: Vapors may travel
considerable distance by air and become ignited by ignition
sources.
Hazardous Combustion Products: Oxides of carbon
Fire Fighting Instructions: Full protective equipment
including self contained breathing apparartus should be
used.
Fire Equipment: Water spray may not be effective, use
fog nozzles |
| Section 6 - Accidental Release Measures |
Spill and Leak Precedure: Eliminate all
ignition sources. Ventilate the area. Use appropriate
respirator and protective clothing.
Small Spills: Contain spill areas with dikes. Recover
spilled material into containers. Absorb remainder with
absorbent material.
Large Spills: If small spill measures do not contain the
spill, notify local authorities and/or the fire department. |
| Section 7 - Handling and Storage |
Handling: Avoid prolonged breathing or contact
with product. Keep containers closed when not in use.
Do not cut, drill, grind, or weld near containers even
when empty. Use non-sparking tools when working around
this material.
Storage Requirements: Keep containers closed when not
in use. Keep away from excessive
heat, open flames, or sparks.
Regulatory Requirments: Consult national, state and local
environmental laws. |
| Section 8 - Exposure Controls / Personal
Protection |
Ventilation: Exhaust as required to keep
exposure below Threshold Limit Values
Protective Gear: If ventilation equipment cannot control
exposures below the TLV's, wear a properly fitted
organic/particulate NIOSH/MSHA approved respirator. Wear
rubber or neoprene protective gloves for repeated or prolonged
skin contact. Wear safety glasses or face shield for eye
protection. |
| Section 9 - Physical and Chemical Properties |
Appearance: Liquid
Odor
Physical State: Liquid
Vapor Density: Heavier then air
Vapor Pressure: 9 mm Hg @ 14C
Evaporation Rate: Faster than ether
Boiling Range: 136 to 202 C
% Volume Volatile: 43.41
Specific Gravity (SG): 1.515
Lbs VOC/Gallon Solids: 5.53
Lbs/Gal VOC Less Exempt Less : water 3.12 |
| Section 10 - Stability and Reactivity |
Stability: Stable
Incompatibility: heat or flames, strong acids or bases.
Strong oxidizing agents
Hazardous Decomposition: Oxides of carbon and nitrogen.
Oxides of carbon |
| Section 11 - Toxicological Information |
Xylenes (o-,m-,p- isomers)
LC 50: Inhalation- 26800 ppm
LD 50: Skin- 2000 mg/kg : Ingestion- 50 g/kg
Ethylbenzene
LC 50: IHL-GPG LCLO 10000 ppm
LD 50: ORL-RAT LD50 3500 mg kg-1 : SKN-RBT LD50 17800
mg kg-1
Stoddard Solvent
LC 50: No information found
LD 50: No information found
Carbon Black
LD 50: oral: >8000 mg/kg |
| Section 12 - Ecological Information |
| Ecotoxicity: Protect environment from spills
and releases. |
| Section 13 - Disposal Considerations |
Disposal: As the US EPA, state, local or
other regulatory agency may have jurisdiction over the
disposal of your
facility's waste, it is incumbent on you, to learn and
satisfy all the regulations which effect you. Dispose
of in accordance to government regulations. |
| Section 14 - Transport Information |
HazardClass
UN Number
Proper Shipping Name
Packing Group
Agency
UN-1263
lll
Flamm Liq
DOT
Paint
*- Flammable Liquid |
| Section 15 - Regulatory Information |
Additional regulatory lisitings where applicable
SARA Section 313 Emission Reporting
1330-20-7 Xylenes (o-,m-,p- isomers) 16.62 percent
100-41-4 Ethylbenzene 4.99 percent
67-56-1 Methyl Alcohol 563 PPM
95-63-6 1,2,4-Trimethylbenzene 527 PPM
Toxic Substances Control Act (TSCA): All chemicals except
those listed below appear in the Toxic Substances Control
Act Chemical Substance Inventory:- None |
| Section 16 - Other Information |
| Every effort has been made to ensure that
the safety information on this sheet is accurate, but
because Chemcoat, Inc. has no control over the condition
under which the product will be used, liability is limited
exclusively to replacement or refund of the purchased
price of this product. Except as stated herein, there
are NO EXPRESS OR IMPLIED WARRANTIES INCLUDING IMPLIED
WARRANTIES OF MERCHANTABILITY OR FINESS FOR A PARTICULAR
PURPOSE. Chemcoat, Inc. assumes no liability for injury
or incidental or consequential damages arising out of
the storage and handling or use of this product. |
| Close
Window |
| Section 1 - Chemical Product and Company
Information |
PRODUCT:
ArmorChem 1500 Universal Red
OBJECT FINISHED: Structural Steel |
PRODUCT NUMBER: 41Y-367 |
Manufactured by:
Chemcoat Inc.
P.O. Box 188
2790 Canfield Lane
Motoursville, PA 17754 |
IN CASE OF EMERGENCY:
Chem-tel
800-255-3924
Chemcoat, Inc.
800-326-9471 |
| Section 2 - Composition / Information on
Ingredients |
Other Exposure Limits
ACGIH Exposure Limits
OSHA Exposure Limits
Chemical Name / CAS No |
The OSHA PELTWA,
NIOSH TWA, DFG MAK,
HSE TWA, and the ACGIH
TWA value is 100 ppm
(435 mg/m3) for all
isomers.
The OSHA PELTWA,
NIOSH TWA, DFG MAK,
HSE TWA, and the ACGIH
TWA value is 100 ppm (435
mg/m3) for all isomers. The
NIOSH, ACGIH, and HSE
STEL value is 150 ppm (655
mg/m3).
The notation "skin" is
added to indicate the
possibility of cutaneous
absorption. The NIOSH
IDLH (all isomers) = 900
ppm.
Xylenes (o-,m-,p- isomers)
1330-20-7
18.34 percent
The OSHA PEL is 100 ppm
(435 mg/m3); there is no
STEL.
The DFG MAK and the HSE
TWA and the ACGIH TWA
value is 100 ppm (435
mg/m3) and the STEL is 125
ppm (545 mg/m3).
The NIOSH IDLH level is
800 ppm . Several states
have set guidelines or
standards for
ethylbenzene in ambient
air ranging from 0.12
mg/m3 (Massachusetts)
to 1.45 mg/m3 (New
York) to 4.35 mg/m3
(Florida, South Carolina)
to 4.35 – 5.45 mg/m3
(North Dakota) to 7.25
mg/m3 (Virginia) to 8.7
mg/m3 (Connecticut) to
10.357 mg/m3 (Nevada).
Ethylbenzene
100-41-4
5.58 percent
The OSHA TWA is 500
ppm (2,900 mg/m3).
ACGIH recommends a TWA
of 100 ppm (525 mg/m3).
NIOSH recommends a
TWA 350 mg/m3 and a
ceiling of 1,800 mg/m3)
not to be exceeded during
any 15 minute work
period.
Stoddard Solvent (1)
8052-41-3
2.06 percent (1) NIOSH recommends a TWA 350 mg/m3 and
a ceiling of 1,800 mg/m3) not to be exceeded during any
15
minute work period. The NIOSH IDLH level is 20,000 mg/m3.
Several states have set guidelines or standards
for Stoddard solvent in ambient air ranging from 5. |
| Section 3 - Hazards Identification |
-
-
0
3
2
HMIS Rating:
2
0
3
Routes of Entry:
Inhalation Skin Contact Eye Contact Ingestion
Exposure to this material may effect the following organs:
Blood Eyes Kidneys Liver Lungs Nervous System Skin |
Effects of Overexposure, Ethylbenzene:
Short Term Exposure
Ethyl benzene irritates the eyes, skin, and respiratory
tract. Exposure to high
concentrations can cause dizziness, lightheadedness and
unconsciousness. Very
high exposures (above the OEL) can cause difficult breathing,
narcosis, coma,
and even death. Swallowing the liquid may cause aspiration
into the lungs,
resulting in chemical pneumonitis. May affect the central
nervous system.
Concentration of 200 ppm can cause irritation.
Long Term Exposure
Repeated or prolonged exposure to the skin may cause drying,
scaling and
blistering. May cause kidney disease, liver disease, chronic
respiratory disease,
skin disease, as follows: EB is not nephrotoxic. Concern
is expressed because the
kidney is the primary route of excretion of EB and its
metabolites. EB is not
hepatotoxic. Since EB is metabolized by the liver, concern
is expressed for these
tissues. Exacerbation of pulmonary pathology might occur
following exposure to
EB. Individuals with impaired pulmonary function might
be at risk. EB is a
defating agent and may cause dermatitis following prolonged
exposure.
Individuals with preexisting skin problems may be more
sensitive to EB. There is
limited evidence that EB may damage the developing fetus,
and may cause
mutations.
Effects of Overexposure, Xylenes (o-,m-,p- isomers):
Short Term Exposure
Inhalation: Exposure to vapor can be irritation to the
nose and throat. Inhalation
of vapor at concentrations above 200 ppm or 3 —
5 minutes can lead to xylene
intoxication. Symptoms include headache, dizziness, nausea
and vomiting. If
exposure should continue, central nervous system depression
characterized by
shallow breathing and weak pulse can occur. Levels of
230 ppm for 15 minutes
may cause lightheadedness without loss of equilibrium.
Reversible liver and
kidney damage in man has followed exposure to sudden high
concentrations of
vapor. Such high levels may also give rise to lung congestion.
Exposure to
extremely high concentrations (10,000 ppm or more) of
xylene vapors can lead to
a strong narcotic effect with symptoms of slurred speech,
stupor fatigue,
confusion, unconsciousness, coma, and possible death.
Effects of Overexposure, Xylenes (o-,m-,p- isomers):
Long Term Exposure
Inhalation of xylene vapor and skin contact with liquid
are the two most probable
routes of long term exposure. Symptoms of inhalation are
dizziness, headache
and nausea. Long term exposure has been associated with
liver and kidney
damage, intestinal tract disturbances and central nervous
system depression.
Prolonged contact with skin can lead to irritation, dryness
and cracking. Repeated
exposure can cause poor memory, difficulty in concentration,
and other brain
effects. It can also cause damage to the eye surface.
Effects of Overexposure, Stoddard Solvent:
Short Term Exposure
Inhalation: Causes irritation of the eyes and respiratory
tract. Exposure to levels
above 2,400 mg/m3 may cause headache, dizziness and nose
and throat irritation.
More severe exposures may cause nausea and vomiting, a
feeling of intoxication,
weakness, muscle twitches and in extreme cases convulsions,
unconsciousness
and death.
Long Term Exposure
Prolonged or repeated contact with liquid may cause defatting
of the skin with
drying, irritation, and skin ulcers. Exposure to vapor
may cause eye, nose and
throat irritation, fatigue, headaches, anemia, jaundice,
and damage to the liver and
bone marrow. In animals: kidney damage. Repeated exposure
may cause a rare
reaction in some people that destroys blood cells (aplastic
anemia). This can be
fatal. Many petroleum-based solvents have been shown to
cause brain and/or
nerve damage. Effects may include reduced memory and concentration,
personality changes, fatigue, sleep disturbances, reduced
coordination, effects on
the autonomic nerves and/or nerves to the limbs.
Carcinogenicity: The following chemicals comprise 0.1%
or more of this mixture and are listed and/or classified
as
carcinogens or potential carcinogens by NTP, IARC, OSHA,
or ACGIH. |
| Section 4 - First Aid Measures |
INHALATION - Move person to fresh air. If
breathing has stopped, administer artifical respiration.
Seek medical
attention!
EYE CONTACT - In case of eye contact, flush the eyes with
water for fifteen (15) minutes. If contact lenses are
worn, quickly remove them, then flush the eyes with water.
Have a physician examine the eyes.
SKIN CONTACT - In case of skin contact, remove contaminated
clothing. Flush the skin with large amounts of water,
then wash the skin with soap and water.
INGESTION - Do not induce vomiting. This may cause chemical
pneumonitis and pulmonary edema. If vomiting occurs spontaneously,
keep the head below the hips to prevent aspiration of
liquid into the lungs. Seek immediate medical attention. |
| Section 5 - Fire Fighting Measures |
Flash Point: 27 C (80 F)
LEL: 0.6 %
UEL: 8.0 % |
Extinguishing Media: Use carbon dioxide (CO2), foam,
dry chemical, or water spray/water fog extinguishing system.
Unusual Fire and Explosion Hazards: Vapors may travel
considerable distance by air and become ignited by ignition
sources.
Hazardous Combustion Products: Oxides of carbon
Fire Fighting Instructions: Full protective equipment
including self contained breathing apparartus should be
used.
Fire Equipment: Water spray may not be effective, use
fog nozzles |
| Section 6 - Accidental Release Measures |
Spill and Leak Precedure: Eliminate all
ignition sources. Ventilate the area. Use appropriate
respirator and protective clothing.
Small Spills: Contain spill areas with dikes. Recover
spilled material into containers. Absorb remainder with
absorbent material.
Large Spills: If small spill measures do not contain the
spill, notify local authorities and/or the fire department. |
| Section 7 - Handling and Storage |
Handling: Avoid prolonged breathing or contact
with product. Keep containers closed when not in use.
Do not cut, drill, grind, or weld near containers even
when empty. Use non-sparking tools when working around
this material.
Storage Requirements: Keep containers closed when not
in use. Keep away from excessive
heat, open flames, or sparks.
Regulatory Requirments: Consult national, state and local
environmental laws. |
| Section 8 - Exposure Controls / Personal
Protection |
Ventilation: Exhaust as required to keep
exposure below Threshold Limit Values
Protective Gear: If ventilation equipment cannot control
exposures below the TLV's, wear a properly fitted
organic/particulate NIOSH/MSHA approved respirator. Wear
rubber or neoprene protective gloves for repeated or prolonged
skin contact. Wear safety glasses or face shield for eye
protection. |
| Section 9 - Physical and Chemical Properties |
Appearance: Liquid
Odor
Physical State: Liquid
Vapor Density: Heavier then air
Vapor Pressure: 9 mm Hg @ 14C
Evaporation Rate: Faster than ether
Boiling Range: 136 to 202 C
% Volume Volatile: 46.32
Specific Gravity (SG): 1.507
Lbs VOC/Gallon Solids:6.22
Lbs/Gal VOC Less Exempt Less : water 3.33 |
| Section 10 - Stability and Reactivity |
Stability: Stable
Incompatibility: heat or flames, strong acids or bases.
Strong oxidizing agents
Strong oxidizers
Hazardous Decomposition: Oxides of carbon and nitrogen.
|
| Section 11 - Toxicological Information |
Xylenes (o-,m-,p- isomers)
LC 50: Inhalation- 26800 ppm
LD 50: Skin- 2000 mg/kg : Ingestion- 50 g/kg
Ethylbenzene
LC 50: IHL-GPG LCLO 10000 ppm
LD 50: ORL-RAT LD50 3500 mg kg-1 : SKN-RBT LD50 17800
mg kg-1
Stoddard Solvent
LC 50: No information found
LD 50: No information found |
| Section 12 - Ecological Information |
| Ecotoxicity: Protect environment from spills
and releases. |
| Section 13 - Disposal Considerations |
Disposal: As the US EPA, state, local or
other regulatory agency may have jurisdiction over the
disposal of your
facility's waste, it is incumbent on you, to learn and
satisfy all the regulations which effect you. Dispose
of in accordance to government regulations. |
| Section 14 - Transport Information |
HazardClass
UN Number
Proper Shipping Name
Packing Group
Agency
UN-1263
lll
Flam Liq*
DOT
Paint
*- Flammable liquid |
| Section 15 - Regulatory Information |
Additional regulatory lisitings where applicable
SARA Section 313 Emission Reporting
1330-20-7 Xylenes (o-,m-,p- isomers) 18.34 percent
100-41-4 Ethylbenzene 5.58 percent
67-56-1 Methyl Alcohol 543 PPM
95-63-6 1,2,4-Trimethylbenzene 509 PPM
Toxic Substances Control Act (TSCA): All chemicals except
those listed below appear in the Toxic Substances Control
Act
Chemical Substance Inventory:- None |
| Section 16 - Other Information |
| Every effort has been made to ensure that
the safety information on this sheet is accurate, but
because Chemcoat, Inc. has no control over the condition
under which the product will be used, liability is limited
exclusively to replacement or refund of the purchased
price of this product. Except as stated herein, there
are NO EXPRESS OR IMPLIED WARRANTIES INCLUDING IMPLIED
WARRANTIES OF MERCHANTABILITY OR FINESS FOR A PARTICULAR
PURPOSE. Chemcoat, Inc. assumes no liability for injury
or incidental or consequential damages arising out of
the storage and handling or use of this product. |
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